全文获取类型
收费全文 | 102篇 |
免费 | 11篇 |
国内免费 | 20篇 |
专业分类
化学 | 71篇 |
晶体学 | 14篇 |
力学 | 2篇 |
综合类 | 1篇 |
数学 | 16篇 |
物理学 | 29篇 |
出版年
2023年 | 2篇 |
2021年 | 2篇 |
2020年 | 1篇 |
2017年 | 1篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 11篇 |
2012年 | 4篇 |
2011年 | 3篇 |
2010年 | 5篇 |
2009年 | 4篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 7篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1977年 | 3篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1938年 | 1篇 |
1931年 | 2篇 |
排序方式: 共有133条查询结果,搜索用时 812 毫秒
51.
Gopal Joshi CI Sujo Bhuban Sahu Ashutosh Pandey Ajith Kumar Jitendra Karande 《Pramana》2002,59(6):1035-1040
A resonator controller has been implemented to stabilize the amplitude and phase of rf fields in the super-conducting resonators
of NSC LINAC. Due to reduced losses these resonators have intrinsic band width of the order of 0.1 Hz at 97 MHz whereas the
vibration-induced center frequency changes are of the order of a few tens of hertz. In the control strategy followed, the
resonator is made the frequency selective part of an oscillator. The phase lock is achieved by dynamically adding a phase
shift in the oscillator. A slow tuner minimizes the slow drifts in the resonator center frequency. In this paper we present
the control strategy, implementation details and performance obtained with this controller. 相似文献
52.
F. J. Himpsel H. Akatsu J. A. Carlisle D. G. J. Sutherland I. Jimenez L. J. Terminello J. J. Jia T. A. Callcott M. G. Samant J. Sthr D. L. Ederer R. C. C. Perera W. Tong D. K. Shunh 《Progress in Surface Science》1995,50(1-4):37-51
A third generation of synchrotron radiation facilities is coming on line worldwide, whose brilliance exceeds previous ultraviolet and x-ray light sources by four orders of magnitude. The capabilities at second and third generation light sources are discussed, using examples in surface and interface chemistry and magnetic nanostructures. The authors' experience at the IBM-Tennessee-Tulane-LLNL-LBL undulator beam line will serve as a hands-on guide for work at one of the new facilities. 相似文献
53.
54.
55.
A fluoroimmunoassay method using unlabeled Terbium chelate isdescribed.The principle is similar to that of fluoroimmunoassay method usinglanthanide chelate as labels.The procedure is simpte because labeling processis unnecessary.The recovery of HSA and albumin in urine is 107% and95% respectively.The standard deviation is tess than 10%. 相似文献
56.
Jason E. Bara Christopher J. Gabriel Evan S. Hatakeyama Trevor K. Carlisle Sonja Lessmann Richard D. Noble Douglas L. Gin 《Journal of membrane science》2008
Solid, polymer membranes fabricated from room-temperature ionic liquid monomers containing oligo(ethylene glycol) or nitrile-terminated alkyl substituents tethered to imidazolium cations were found to exhibit ideal CO2/N2 and CO2/CH4 separation factors significantly greater than those with comparable length n-alkyl substituents, with similar CO2 permeability. Polymers containing these functional groups exhibited CO2/N2 gas separation performance exceeding the “upper bound” of a “Robeson Plot”. 相似文献
57.
58.
The AT&T single mode ST® connector is a low-loss, low-reflection connector suitable for high-speed, wideband digital transmission. This new connector offers enhanced hardware for easier use and more stable connections. In addition, a new backplane-compatible version is introduced for circuit board applications. The insertion loss of AT&T's single mode ST connector averages 0.34 dB with a standard deviation of 0.28. The reflection of an AT&T ST connection (product against product) averages -42.8 dB with a worst case of -34.1 dB. The environmental performance of the connector is characterized by low variations in loss and refection. The AT&T single mode ST connector and its backplane version were subjected to a battery of tests whose results are discussed in this article. 相似文献
59.
Taratula O Rochford J Piotrowiak P Galoppini E Carlisle RA Meyer GJ 《The journal of physical chemistry. B》2006,110(32):15734-15741
Phenylenethynylene (PE) rigid linkers (para and meta) were used to anchor pyrene to the surface of TiO2 (anatase) and ZrO2 nanoparticle thin films through the two COOH groups of an isophthalic acid (Ipa) unit. Four chromophore-linker models were studied in solution and bound. Two are novel meta-pyrene-PE linker systems: dimethyl 5-(3-(1-pyrenylethynyl)phenylethynyl)-isophthalate, carrying one pyrene, and dimethyl 5-(bis-3,5-(1-pyrenylethynyl)phenylethynyl)-isophthalate, carrying two. These were compared with para rigid-rods dimethyl 5-(1-pyrenylethynyl)isophthalate and dimethyl 5-(4-(1-pyrenylethynyl)phenylethynyl)-isophthalate, each carrying one pyrene but varying in length. The length of the PE linkers and the para or meta substitution influence the photophysical properties of the compounds. The extinction coefficient increased, and the long wavelength absorbance of the pyrene chromophore was shifted to the red with increasing conjugation. Compared to unsubstituted pyrene, the pyrene-linker systems were characterized by short fluorescence lifetimes (tau approximately 2 ns in tetrahydrofuran solutions), but quantum yields were close to unity. ZINDO/S CI calculations attribute this effect to a switching in the order of the two lowest-lying singlet states of pyrene. High surface coverages, approximately 10(-8) mol/cm2, and carboxylate binding modes on nanostructured TiO2 films were obtained in all cases. The appearance of a pyrene excimer emission on ZrO2, an insulator, indicates that the pyrene-linker system is closely packed (Py-Py < 4 A) on the surface. The fluorescence emission on TiO2 was completely quenched, consistent with quantitative and rapid electron injection into the semiconductor indicating that the pyrene excimer acts as a sensitizer. Photoelectrochemical studies in regenerative solar cells with I3-/I- as the redox mediator indicated near-quantitative conversion of absorbed photons into an electrical current. 相似文献
60.
Nevin N. Naguib Jeffrey W. Elam James Birrell Jian Wang David S. Grierson Bernd Kabius Jon M. Hiller Anirudha V. Sumant Robert W. Carpick Orlando Auciello John A. Carlisle 《Chemical physics letters》2006,430(4-6):345-350
Extremely smooth (6 nm RMS roughness over 4 μm2), thin (100 nm), and continuous ultrananocrystalline diamond (UNCD) films were synthesized by microwave plasma chemical vapor deposition using a 10 nm tungsten (W) interlayer between the silicon substrate and the diamond film. These UNCD films possess a high content of sp3-bonded carbon. The W interlayer significantly increased the initial diamond nucleation density, thereby lowering the surface roughness, eliminating interfacial voids, and allowing thinner UNCD films to be grown. This structural optimization enhances the films’ properties and enables its integration with a wide variety of substrate materials. 相似文献